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As of the 2013 Census Estimate, it had a population of 50,821, making it the most populous city in the state, while its metropolitan area had 224,743 residents.

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Later, coal became central to economic prosperity in the city and the surrounding area. In 1791, Daniel Boone was a member of the Kanawha County Assembly.

It is a center of government, commerce, and industry.

Daniel Boone, who was commissioned a lieutenant colonel of the Kanawha County militia, was elected to serve in 1791 in the Virginia House of Delegates.

As told in historical accounts, Boone walked all the way to Richmond.

By 1808, 1,250 pounds of salt were being produced a day.

An area adjacent to Charleston, Kanawha Salines, now Malden, would become the top salt producer in the world.

Today, trade, utilities, government, medicine, and education play central roles in the city's economy. Charleston is the home of the West Virginia Power minor league baseball team, the West Virginia Wild minor league basketball team, and the annual 15-mile (24 km) Charleston Distance Run.

Yeager Airport and the University of Charleston are also located in the city.

Although the Confederate States Army was victorious, occupation of the city was short-lived.

Union troops returned just six weeks later and stayed through the end of the war.

In 1818, Kanawha Salt Company, first trust in United States, went into operation.

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